Spectrophotometric determination of nickel in biological samples using 1-azobenzene-3-(3-hydroxyl-2-pyridyl)-triazene

A new sensitive and selective chromogenic reagent, 1-azobenzene-3-(3-hydroxyl-2-pyridyl)-triazene (ABHPT), was synthesized. It has been found that ABHPT reacts with nickel(II) in a borax buffer solution (pH 10.0) to form 2: 1 red complexes with the maximum absorption at 530 nm. The apparent molar absorptivity of the complex is 2.6 × 10⁵ L/(mol cm). Most metal ions can be tolerated in considerable amounts, whereby only zinc and mercury may interfere with the determination of nickel(II). Nevertheless, this can be easily eliminated by prior separation with sulfhydryl dextran gel. A new method for the spectrophotometric determination of trace nickel(II) was developed. Beer’s law is obeyed for 0–15 μg of nickel(II) in 25 mL of solution. The limit of quantification, limit of detection, and relative standard deviation are 0.74 ng/mL, 0.25 ng/mL, and 1.0%, respectively. The method has been applied to the determination of trace nickel(II) in biological samples with satisfactory results. The text was submitted by the authors in English.     

甲基、氨基和甲胺在清洁及C(N,O)改性的Mo(100)表面的吸附

采用广义梯度近似(GGA)的密度泛函理论(DFT), 并结合平板模型, 研究了甲基、氨基和甲胺在清洁及C(N, O)改性的Mo(100)面的吸附行为. 计算结果表明, 在较低覆盖度下(θ=1/6 ML(monolayer)), 吸附物种在不同表面上的稳定吸附位的吸附能变化不大; 而在较高覆盖度下(θ=1/4 ML), 其稳定的吸附位置可能发生变化, 且吸附能有了明显的区别. 它们在改性的Mo(100)表面吸附能较清洁表面小, 并且按C、N、O的顺序降低. 究其原因可归结为C、N、O性原子的存在使得金属表面的供电子能力减弱, 从而导致金属的d带中心的下移. 通过对金属Mo的d带性质的分析, 发现d带中心只能笼统地说明改性原子对于清洁表面的性质有一定的影响, 不能很好地体现C、N、O对于清洁表面性质影响的差异, 而dz2轨道的能量中心却能很好地反映出吸附物种在改性表面上的吸附能按C、N、O的顺序依次减小这一规律.     

Selective solid-phase extraction of trace cadmium(II) with an ionic imprinted polymer prepared from a dual-ligand monomer

A novel dual-ligand reagent (2Z)-N,N′-bis(2-aminoethylic)but-2-enediamide, was synthesized and applied to prepare metal ion-imprinted polymers (IIPs) materials by ionic imprinted technique for selective solid-phase extraction (SPE) of trace Cd(II) from aqueous solution. In the first step, Cd(II) formed coordination linkage with the two ethylenediamine groups of the synthetic monomer. Then the complex was copolymerized with pentaerythritol triacrylate (crosslinker) in the presence of 2,2′-azobisisobutyronitrile as initiator. Subsequently, the imprinted Cd(II) was completely removed by leaching the dried and powdered materials particles with 0.5 M HCl. The obtained IIPs particles exhibited excellent selectivity for target ion. The distribution ratio (D) values of Cd(II)-IIPs for Cd(II) were greatly larger than that for Cu(II), Zn(II) and Hg(II). The relative selective factor (α_r) values of Cd(II)/Cu(II), Cd(II)/Zn(II) and Cd(II)/Hg(II) were 25.5, 35.3 and 62.1. The maximum static adsorption capacity of the ion-imprinted and non-imprinted sorbent for Cd(II) was 32.56 and 6.30 mg g⁻¹, respectively. Moreover, the times of adsorption equilibration and complete desorption were remarkably short. The prepared Cd(II)-IIPs were shown to be promising for solid-phase extraction coupled with inductively coupled plasma atomic emission spectrometry (ICP-AES) for the determination of trace Cd(II) in real samples. The precision (R.S.D.) and detection limit (3σ) of the method were 2.4% and 0.14 μg L⁻¹, respectively. The column packed with Cd(II)-IIPs was good enough for Cd(II) separation in matrixes containing components with similar chemical behaviour such as Cu(II), Zn(II) and Hg(II).     

Generating Majorana modes in one-dimensional p-wave superconductor with second-neighbor couplings by periodic kicking

Generating many Majorana modes (MMs) within one single system is a constructive method for experimental observation of MMs in condensed-matter systems. In this paper, we show that by adding periodic δ-function kicks on the chemical potential, a large number of MMs can be generated in the one-dimensional p-wave superconductor system with second-neighbor couplings. The Floquet theory has been used to analyze the stroboscopic properties and the winding number can be used to characterize the topological properties. We have analyzed the influence of the kicking parameters and second-neighbor couplings on the topological phase transitions.     

Periodic Driving Induced Anomalous End Modes in a Superconducting Wire with the Second-Neighbor Pairing Potential

The anomalous end modes are generated in a one-dimensional p-wave superconducting wire with second-neighbor couplings and a periodic driving in pairing potential. We show that the driving on the amplitude or the phase of the first-neighbor and second-neighbor pairing potential can both generate conventional end modes and anomalous end modes, with corresponding Floquet eigenvalues equal to ± 1 or appear in complex conjugate pairs. We have numerically studied the driving of the first-neighbor and second-neighbor pairing potential, and also analyzed the end modes, Floquet eigenvalues and the Fourier transform of these end modes.

     

氮掺杂的石墨烯作为钠离子电池负极材料的第一性原理研究

采用基于密度泛函理论的第一性原理方法,研究了本征石墨烯、氮掺杂的石墨烯和叽咯石墨烯吸附钠原子的电荷密度、吸附能、态密度和储存量.结果表明,三种石墨烯中,钠原子的最佳吸附位置为H位.与本征石墨烯相比,氮掺杂的石墨烯对钠原子的吸附能提高,叽咯石墨烯对钠原子的吸附能是-3.274 eV,约为本征石墨烯对钠原子吸附能的1.7倍.钠原子与叽咯石墨烯中的氮原子发生轨道杂化,而与本征石墨烯和氮掺杂的石墨烯没有发生轨道杂化现象.叽咯石墨烯能够吸附10个钠原子,与本征石墨烯相比显著提高,氮掺杂的石墨烯只能吸附4个钠原子.因此,叽咯石墨烯有望成为一种潜在的储钠材料.     

有限群的$\Phi$-$\tau$-可补子群

假设$\tau$是一个子群算子, $H$是有限群$G$的一个$p$-子群. 令 $\bar{G}=G/H_{G}$且$\bar{H}=H/H_{G}$, 如果$\bar{G}$有一个次正规子群$\bar{T}$ 和一个包含于$\bar{H}$ 的$\tau$-子群$\bar{S}$满足$\bar{G}=\bar{H}\bar{T}$且$\bar{H}\cap\bar{T}\leq \bar{S}\Phi(\bar{H})$, 就称$H$是$G$的一个$\Phi$-$\tau$- 可补子群. 文章通过讨论群$G$的准素数子群的$\Phi$-$\tau$-可补性给出了超循环嵌入和$p$-幂零性的一些新的特征.     

Hawking radiation of five-dimensional rotating black hole

Applying the Damour–Ruffini method, we have considered the Hawking radiation of the five-dimensional rotating black hole. When taking the energy conservation and angular momentum conservation into consideration and considering the reaction of the radiation of the particle to spacetime, we see that the exact radiation spectrum is not purely thermal and the angular momentum of the black hole is quantized.     

Hawking radiation of Kerr–Newman–de Sitter black hole

We extend the classical Damour–Ruffini method and discuss Hawking radiation in Kerr–Newman–de Sitter (KNdS) black hole. Under the condition that the total energy, angular momentum and charge of spacetime are conserved, taking the reaction of the radiation of the particle to the spacetime and the relation between the black hole event horizon and the cosmological horizon into consideration, we derive the black hole radiation spectrum. The radiation spectrum is no longer a pure thermal one. It is related to the change of the Bekenstein–Hawking entropy corresponding the black hole event horizon and the cosmological horizon. It is consistent with the underlying unitary theory.     

铋膜电极溶出伏安法测定苍耳子中锌的含量

采用电位溶出法,用铋膜电极替代汞膜电极对中药苍耳子中微量元素锌的测定作了研究,考察了同位镀铋膜及测定微量元素锌的条件。实验结果表明：锌在以KSCN为支持电解质的铋膜电极上可得到灵敏的电位溶出峰,线性方程为：为I=2.0062C＋0.0069,相关系数为r=0.9967,检出限为6.0×10-8g/L线性范围为0.5×10-6—2.8×10-6mol/L,RSD=2.24%。该法简单快速,准确度和精密度均符合要求,回收率为89.5%—100.3%。